Exascale Computing Project (ECP) Software Technologies (ST) software, Extreme-scale Scientific Software Stack (E4S) v22.05, includes a subset of ECP ST software products, and demonstrates the target approach for future delivery of the full ECP ST software stack. Also available are a number of ECP ST software products that support a Spack package, but are not yet fully interoperable. As the primary purpose of the v22.05 is demonstrating the ST software stack release approach, not all ECP ST software products were targeted for this release. Software products were targeted primarily based on existing Spack package maturity, location within the scientific software stack, and ECP SDK developer experience with the software. Each release will include additional software products, with the ultimate goal of including all ECP ST software products.